ExhibitA_SpecsCombined
Version: 011656/1.0
Date of issue: March 2002
Atlac E-Nova RE 3475
Atlac E-Nova
Atlac E-Nova is an evolutionary development
building on 40 years of unsaturated polyester and
epoxy vinyl ester (urethane) technology. Atlac E-
Nova results in resin systems tailored to the needs
of customers and end-users, offering enhanced
properties over currently available vinyl ester resins.
Major applications
Atlac E-Nova RE 3475 has been specifically
developed for UV-curable pipe rehabilitation
systems.
Chemical/physical nature
Atlac E-Nova RE 3475 is an epoxy bisphenol A vinyl
ester urethane especially modified for thickening
with magnesium oxide, dissolved in styrene.
Principal properties
Atlac E-Nova RE 3475 has a high reactivity,
medium viscosity and it can readily be thickened
with magnesium oxide.
Atlac E-Nova RE 3475 can be cured with both
conventional curing agents and with low energy UV-
light (365 - 420 nm), yielding pipes with very good
mechanical properties, high resistance to heat
deformation and excellent chemical resistance.
Product specifications
Property Range Unit TM
Viscosity, 23°C 650 - 750 mPa.s 2013
Solids content, IR 51 - 54 % 2024
Appearance clear - sl. hazy - 2265
Water content 0.1 - 0.25 % 2350
Peak time 4.0 - 7.0 Minutes 2500
Peak temperature 180 - 220 °C 2500
Remarks
TM 2013, Physica, Spindle Z 2, 100 s-1
Reactivity determined with Ultra-Vitalux test lamp (300 Watt, fa.
Osram)
Properties of the liquid resin (typical values)
Property Value Unit TM
Density, 23°C appr. 1080 kg/m³ 2160
Flash point appr. 33 °C 2800
Stability, no init., dark, 25°C 3 months -
Properties of cast unfilled resin (typical values)
Property Value Unit TM
Tensile strength 81 MPa ISO 527-2
Tensile E-modulus 3.6 GPa ISO 527-2
Elongation at break 3.5 % ISO 527-2
Flexural strength 155 MPa ISO 178
Flexural E-Modulus 3.7 GPa ISO 178
Heat deflection temp. (HDT) 145 °C ISO 75-A
Impact res. - unnotched sp. 13 kJ/m² ISO 179
Curing conditions
The curing characteristics are obtained using 0,3% NL51P and 1%
Butanox M50 (AKZO). All test samples were post cured for 3 hrs at
100°C and 1 hr. at 150°C
Processing
Atlac E-Nova RE 3475 can be cured with low energy
UV-light (wavelength 365 - 420 nm) or conventionally
with usual curing agents. If the resin is not exposed to
direct daylight processing time may be extenuated to
several hours. Curing in places that are not directly
exposed to day- or UV-light can be assisted by adding
e.g. 0,5 % t-butylperoxy-2-ethyl-hexanoate (e.g.
Trigonox 21, AKZO-Nobel). Addition of a small amount
of peroxide is recommended for all applications that
require a low residual styrene content.
Post curing at elevated temperatures for several hours
if small amounts of peroxides have been added to the
resin may optimise the final state of cure.
Guidelines before use
The resin should be conditioned at a well-defined
application dependant temperature.
Storage guidelines
Atlac E-Nova RE 3475 should be stored indoors in the
original, unopened and undamaged packaging in a dry
place at temperatures between 5°C and 30°C.
The shelf life of styrene containing unsaturated
polyesters will be significantly reduced when exposed
to light and/or higher temperatures. Store in dark and in
100% light tight containers only.
Material Safety
A Material Safety Data Sheet of this product is
available on request.
Test methods
Test methods (TM) referred to in the table(s) are
available on request
Although the facts and suggestions in this publication are based on our own research and are believed reliable, we cannot assume any responsibility for performance or results obtained through the use of our
products herein described, nor do we accept any liability for loss or damages directly or indirectly caused by our products. The user is held to check the quality, safety and all other properties of our product prior to use. Nothing herein is to be taken as permission, inducement or recommendation to practise any patented invention without a license.
Product data
Head office: DSM Composite Resins AG - P.O. Box 1227 - 8207 Schaffhausen - SwitzerlandTel. (+41) (0)52 – 6441212 - Fax. (+41) (0)52 – 6441200 - Internet site:www.dsmresins.com
DSM Composite Resins
osmic
TopHat,LLC
Top Hat Lateral Connection Sealing System
SUBMITTAL
The Top I hit Lateral Connection System is designed to transport,install and cure a
factory resin impregnated ECU fiberglass laminate to seal the lateral to the sewer main.
HAT
TM
LATERAL CONNECTION SEALING SYSTEM
Before After
Cos in it TopHat,LLC •3055 Kashma Street •I orrance,California 90505
Tel.:424 588-9872 •E-Mail:tophatchris@gmail.com •Homepage:
www.cosmic.at
osmic
TopHat,"LLC
TOPHATC120E
System Attachments
T^cosmic"
lateralcoknectionseaungsysttiu
Control unir Winch
TonHat
UV-ContioI unit L
H—"^
Cutting
E-Control unit
C.with Parallel Extension
C.with Extension
Cosmic TopHat,LLC •3055 Kashiwa Streel ■Torranee, California 90505
Tel.:424 558-9872 •E-Mail:lophatchris@gm:iil.com •Hoinepsige:www.cosmic.at
COSMIC TopHat
LATERAL CONNECTION SEALING SYSTEM
EQUIPMENT
Camera
Pressure
gauge
LED lamps
TopHat Packer
A hood packer
Chassis with gear unit
C120
Control panel and
electronics for TopHat
andC120
GENERAL SPECIFICATION FOR THE REHABILITATION OF
SEWER LATERAL TO SEWER MAIN
Service Lateral Connections (SLC)
1.General:
It is the intent of this specification to provide for the rehabilitation of the existing service lateral
connection (SLC)to the main sewer,without excavation,by the installation ofa (UV)light curing,
resin impregnated,flexible fiberglass insert (top hat)that is pushed into the house connection pipe,
using a mainline robot crawler connected to a packer.The SLC may be a combination of "tees"or
"wyes"of varying angles.The resin shall be rapidly cured to transform the flexible insert into a hard,
impermeable seal around and in the lateral connection.When cured,SLC shell seal the connection
ofthe lateral to the mainline in a continuous tight-fitting,watertight pipe-within-a-pipe to eliminate
any visible ground water leakage between the lateral and mainline,and shall provide a leak-proof
seal designed to prevent root intrusion,infiltration,and ex-filtration between a liner and host pipe.
2.General Corrosion Requirements:
The finished SLC product shall be fabricated from materials which when cured will be chemically
resistant to withstand internal exposure to domestic sewage and shall meet the chemical resistance
requirements ofASTM D-543.
The SLC product shall be compatible with the lining system materials utilized in the main sewer
line.
3.SLC Materials:
The SLC product shall be an ECR (E-glass corrosion resistant)fiberglass laminate.The fiberglass
material is factory impregnated with polyester or Vinyl Ester resins that are UV light reactive.When
the laminate is mounted on the packer,epoxy or other adhesive products shall be used to secure a
permanent bond between the laminate and liner and the existing lateral pipe.
This specification references The American Society for Testing and Materials (ASTM)standards
that are made part hereof by reference and shall be the latest edition and revision.
D-543 Testing Method of Plastics to Chemical Regents
D-578 Standard Specifications for Glass Fiber Strands
D-l 600 Abbreviations of Terms Relating to Plastics
D-638 Testing Methods for Tensile Properties of Plastics
D-790 Test Methods for Flexural Properties of Un-reinforced and Reinforced Plastics and
Electrical Insulating Materials
Reference is further made to NASSCO Standards:Recommended Specification for Sewer Collection
Systems Rehabilitation.
4.Physical Properties:
The cured SLC shall conform to the minimum standards as follows:
Flexural Modulus ofElasticity:ASTMD-790 725,000 psi (minimum)
Flexural Strength at Break (fiber stress)ASTMD-790 6,500 psi (minimum)
Tensile Strength at Break:ASTMD-638 9,000 psi (minimum)
Bonding materials used with SLC sealing system shall be compatible with the existing mainline
and house connection or with the lining system used in the mainline and lateral.
5.Installation Preparation:
The Contractor shall carry out its operations in strict accordance with all OSHA standards and
City's guidelines.Particular attention is drawn to those safety requirements involving entering
confined spaces.
Prior to installing the SLC product the area around the lateral sealing surface in both the main and
lateral shall be inspected.Waste product build-up,hard scale,roots,lateral cutting debris or resin
slugs must be removed by using high pressure waterjetting or in-line robotic cutters.
Break-in connection and /or lateral pipe protruding into.the mains shall be ground flush to the
mainline.Built-up deposits on the main and lateral pipe walls shall be removed.The removal shall
reach at least one foot beyond the SLC product to allow the bladder to inflate tightly against the pipe
walls ensuring a smooth transition from the SLC product to the existing pipe wall.
In relined pipes,the lateral reinstatement must be opened 95 percent or more,and shall have a
smooth finished edge.Over-cuts shall not exceed one inch beyond the internal diameter of the
lateral.
When necessary,the Contractor shall provide for the flow bypassing of sewage around the section
or sections of mainline pipe where the service lateral designated for SLC is located.The bypass shall
be made by plugging the line at an existing upstream manhole and pumping the flow into a
downstream manhole or adjacent system.The pump and bypass line shall be of adequate capacity
and size to handle the flow.
6.Installer Qualification:
The installer shall be certified by the manufacturer ofthe SLC sealing system.Personnel installing
the SLC sealing system shall be adequately trained in maintenance and operation of the required
installation equipment.A letter from the manufacturer of the SLC sealing system,verifying the
certification ofthe installer,shall be submitted to the owner.
7.SLC Installation:
The resin impregnated SLC product shall be loaded on the applicator apparatus,attached to a
robotic devise and positioned in the mainline pipe at the service connection that is to be sealed.The
robotic device together with a television camera shall be used to align the SLC repair product with the
service connection opening.Air pressure,supplied to the applicator through an air hose,shall be used
to insert the resin impregnated SLC product into the lateral pipe.The inserted product will then be
inspected using a TV camera to confirm the SLC product is correctly positioned and /or centered in the
lateral opening prior to curing.The insertion pressure will be adjusted to fully deploy the SLC product
into the lateral connection and hold the SLC product tight to the main and lateral pipe walls.Care shall
be taken during the curing process not to over-stress the bladder.
The pressure apparatus shall include a bladder of sufficient length in both the main and lateral lines
such that the inflated bladder extends beyond the ends of both the lateral tube and main line brim
segment of the SLC product pressing the edges flat against the internal pipe wall thus forming a smooth
transition from SLC product to pipe diameters without a step,ridge or gap between the SLC product and
the inner diameter of the lateral and mainline pipe.
After insertion is completed,recommended pressure must be maintained on the SLC product for the
duration ofthe UV light curing process.
The bladder is then deflated,removed from the sealed connection and returned to the manhole to
repeat the cycle.
The finished SLC product shall be free of dry spots,lifts,and de-lamination.The installed SLC shall
not inhibit the closed circuit television post video inspection of the mainline or service lateral pipes.
After the work is completed,the Contractor will provide the customer with a video disc showing the
completed work including the restored conditions.
During the warranty period any defects with the SLC that affect the performance or cleaning of the
lateral connection shall be repaired at the contractor's expense in a manner acceptable to the customer.
8.CleanUp:
Upon acceptance of the installation work,the contractor shall reinstate the site affected by its
operations to as close to the original condition as possible.
HTS Pipe Consultants,Ine.
420 Picturing Street.Houston.TX 77091
www.htsplpeconsultanls.com
Phono 713-692-8373
Fax 713-692-8502
Ton Free 1-800-692-TE8T
August 2,2010
HTS Report #;ULW02F10.009.doc Revised
Mr.Chris Scarratt
Cosmic Tophat LLC
4025 Spencer,Suite 403
Tonance,CA 90503
Customer Project Name:
Resin:
Date Sample Received:
Date Sample Tested:
Top-Hat Material
Polyester BASF-PALATAL P 921-02
9/11/02
9/11/02
2 Plate samples were delivered to HTS'laboratory for testing.The samples were tested in accordance with ASTM D638
Type II and ASTM D790 Method I Procedure A.A Support Span-to-Depth Ratio of 16 to 1 was used as specified in the
test standard ASTM D790.Tensile Strength,thickness measurements,flexural stress and flexural modulus of elasticity
tests were performed on each sample.Five (5)specimens were cut and tested from each sample.The results summarized
and reported below are averages ofthe five (5)specimens.A test report for each sample is attached.
SAMPLE
ID
A
B
MANHOLE
TO
MANHOLE
—
—
MAXIMUM
FLEXURAL
FIBER STRESS
(pri)
ASTM D 790
58370.5
39381.0
FLEXURAL
MODULUS OF
ELASTICITY
(pri)
ASTM D 790
1,519,153
1,001,918
STRENGTH @
BREAK
(psi)
ASTM D 638
57500
46170
ELONGATION®
BREAK
(%)
ASTM D 638
13.11
11.39
The following table contains the thickness measurements for each individual specimen tested
MEASUREMENT OF THICKNESS FOR CURED IN PLACE PIPE LINER
ASTM D 2122
Sample
ID
A
B
Manhole to
Manhole
—
—
No.1
.084
.080
No.2
.087
.075
No.3
.055
.086
No.4
.062
.094
No.5
.085
.090
No.6
.052
.095
No.7
.065
.082
No. 8
.060
.072
Combined Total
Average/Specimen
in
0.069
0.084
mm
1.7
2.1
Technician
Time
E.Carrillo
4hrs
Sincerely,
Vice President
This test report relates only to the items tested and shall not be reproduced except in foil without approval ofHTS,Inc.
ULW02F10.009R-Page 1 of 1
Serving the Pipe Rehabilitation Industry
HTS,Inc.Consultants
416 Pickering Street,Houston,TX 77091
www.htshouston.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Excellence In Engineering,Consulting,Testing andInspection
PLEXORAL PROPERTIES OF PLASTIC (ASTH D790)
SUPPORT SPAN =I1
Flexural 3 point bend
Operator name:K.PHOUANGSAVANH
Sample Identification:2P10-9-1
Interface Type:42/43/4400 Series
Machine Parameters of test:
Sample Rate (pts/sec):10.000
Crosshead Speed (in/min ):.0300
Instron Corporation
Series IX Automated Materials Testing System 6.05
Test Date:11 Sep 2002
Sample Type:ASTH
Humidity U):50
Temperature (deg.F):
Dimensions:
Spec.1 Spec.2 Spec.3 Spec.4 Spec.5
Hidth (in)
Depth (in)
Span (in)
1.0800
.05000
1.0000
Out of 5 specimens,0 excluded.
Sample comments:A
Specimen
Number
1
2
3
4
5
Hean:
Standard
Deviation:
Minimum:
Maximum:
Displcment
at
Yield
(in)
.1384
.1087
.1509
.1372
.1218
.1314
.0164
.1087
.1509
1.0850 1
.05500 .1
1.0000 1
Strain
at
Yield
(in/in)
.0415
.0359
.0498
.0453
.0460
.0437
.0053
.0359
.0498
.0550 1.0600
15500 .05500
.0000 1.0000
Load
at
Yield
Ubs)
112.1
115.7
118.1
134.0
166.1
129.2
22.3
112.1
166.1
1.0730
.06300
1.0000
Stress
at
Yield
{psi)
62277.8
52877.3
55509.0
62685.2
58503.3
58370.5
4250.4
52877.3
62685.2
Modulus
Of
Elasticity
(psi)
1724142
1617586
1309184
1560563
1384290
1519153.
170073.
1309184.
1724142.
73
•Geotechnical Engineering •Materials Testing and Inspection •Environmental Consulting •Geosynthetics and Construction QA/QC
Serving the Construction,Petroleum and Waste Industries
HTS,Inc.Consultants
416 Pickering Street.Houston.TX 77091
www.htshouston.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Excellence In Engineering,Consulting,Testing and Inspection
FLBXURAL PROPERTIES OP PLASTIC (ASTH D790)
SUPPORT SPAH =1"
Plexural 3 point bend
Operator name:E.PIOUANGSAVANH
Sample Identification:2P10-9-2
Interface Type:42/43/4400 Series
Machine Parameters of test:
Sample Rate (pts/sec):10.000
Crosshead Speed (in/min ):.0300
Instron Corporation
Series IX Automated Materials Testing System 6.05
Test Date:11 Sep 2002
Sample Type:ASTH
Humidity {t ):50
Temperature (deg.F):
Dimensions:
Width (in)
Depth (in)
Span (in)
Out of 5 specimens,0 excluded.
Sample comments:B
Spec,l Spec.2 Spec.3 Spec.4 Spec.5
1.0970 1.0610 1.0850 1.0640 1.0960
.06700 .07200 .07300 .07500 .08200
1.0000 1.0000 1.0000 1.0000 1.0000
Specimen
Nutaber
l
2
3
4
5
Hean:
Standard
Deviation:
Minimum:
Maximum:
Displcment
at
Yield
(in)
.1075
.1102
.1041
.0951
.0872
.1008
.0095
.0872
.1102
Strain
at
Yield
(in/in)
.0432
.0476
.0456
.0428
.0429
.0444
.0021
.0428
.0476
Load
at
Yield
(lbs)
144.8
142.1
148.5
165.7
167.0
153.6
11.8
142.1
167.0
Stress
at
Yield
(psi)
44106.6
38753.0
38525.0
41528.8
33991.4
39381.0
3778.9
33991.4
44106.6
Modulus
Of
Blasticity
(psi)
1227199
874595
1015072
1056811
835914
1001918.
156290.
835914.
1227199.
73
•Geotechnical Engineering •Materials Testing and Inspection •Environmental Consulting •Geosynthetics and Construction QA/QC
Serving the Construction,Petroleum and Waste industries
HTS,Inc.Consultants
416 Pickering Street,Houston,TX 77091
www.htshouston.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Excellence in Engineering,Consulting,Testing and Inspection
TENSILE PROPERTIES OF PLASTICS (ASTH D 638)
TYPE II -6000 LBS CELL
Test type:Tensile
Operator name:E.C
Sample Identification:2F10-9T1
Interface Type:42/43/4400 Series
Machine Parameters of test:
Sample Rate (pts/sec):10.000
Crossbead Speed (in/rain ):.2000
Instron Corporation
Series IX Automated Materials Testing Systeia 6.05
Test Date:11 Sep 2002
Sample Type:ASTH
Humidity (t ):50
Temperature (deg.P):71
Dimensions:
Width (in)
Thickness (in)
Spec gauge len (in)
Grip distance:(in)
Spec.1 Spec.2 Spec.3 Spec.4 Spec.5
.24200 .21400 .25400 .21100 .20200
.06000 .05600 .07200 .05600 .04700
2.0000 2.0000 2.0000 2.0000 2.0000
5.3000 5.3000 5.3000 5.3000 5.3000
Out of 5 speciiens,0 excluded.
Sample comments:A
Specimen
Number
l
2
3
4
5
ROLL DIR.
Strength
at
Break
(psi)
62140.
44650.
47090.
65620.
68000.
Elongation
at
Break
(1)
15.900
9.500
16.400
11.150
12.600
Mean:57500.13.110
Standard
Deviation:
Minimum:
Maximum:
10860.
44650.
68000.
2.989
9.500
16.400
•Geotechnical Engineering *Materials Testing and Inspection •Environmental Consulting •Geosynthetics and Construction QA/QC
Serving the Construction!Petroleum and Waste industries
HTS,Inc.Consultants
416 Pickering Street,Houston,TX 77091
www.htshouston.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Excellence In Engineering,Consulting,Testing and Inspection
TENSILE PROPERTIES OF PLASTICS (ASTH D 638)
TYPE II -6000 LBS CELL
Test type:Tensile
Operator name:E.C
Sample Identification:2P10-9T2
Interface Type:42/43/4400 Series
Machine Parameters of test:
Sample Rate {pts/sec):10.000
Crossbead Speed (in/min }:.2000
Instron Corporation
Series IX Automated Materials Testing System (.05
Test Date:11 Sep 2002
Sample Type:ASTH
Humidity (I ):50
Temperature (deg.F):71
Dimensions:
Width (in)
Thickness (in)
Spec gauge len (in)
Grip distance:(in)
Spec.1 Spec.2 Spec.3 Spec.4 Spec.5
.23000 .25500 .24300 .22900 .23800
.06500 .06300 .06500 .07000 .06000
2.0000 2.0000 2.0000 2.0000 2.0000
5.3000 5.3000 5.3000 5.3000 5.3000
Out of 5 specimens,0 excluded.
Sample comments:B
Specimen
Number
1
2
3
4
5
ROLL DIR.
Strength
at
Break
(psi)
50120.
44240.
39300.
43B30.
53350.
Elongation
at
Break
(1)
11.90
10.90
10.65
11.15
12.35
Hean:46170.11.39
Standard
Deviation:
Minimum:
Maximum:
5558.
39300.
53350.
.71
10.65
12.35
>Geotechnical Engineering •Materials Testing and Inspection •Environmental Consulting •Geosynthetics and Construction QA/QC
Serving the Construction,Petroleum and Waste Industries
HTS Pipe Consultants,Inc.Phone 713-692-8373
420 Pickering Street,Houston,TX 77091 Fax 713-692-8502
vww.htspipeconsultants.com Toll Free 1-800-692-TEST
June 13,2011
Mr.Chris Scarratt
Cosmic Top Hat LLC
3055 Kashiwa St.
Torrance,CA 90505
Re:Chemical Resistance Testing
E-Glass (Owen Corning)
Polyester Base -Palatel P92-1-02
Dear Mr.Scarratt:
Please find attached results of Chemical Resistance Tests performed in our laboratory.The tests were performed in accordance with ASTM D543 and ASTM F1216,SectionX2"Chemical Resistance Tests".One sample was used for base line testing and eightsampleswereexposedto8differentchemicalsolutionsfor30daysat714degreesF.
The eight chemical solutions were as specified in table X2.1 of ASTM F1216.
The specification states that the CIPP test specimens should lose no more than 20%of
their initial flexural strength and flexural modulus.As indicated in the attached Summary
ofTest Data,all of the test samples complied with this specification.
If you have any questions or comments,please call.
Sincerely,
HTS PIPE CONSULTANTS,INC.L
Larry L.McMichael
PrincipalF/HTSP!PE/l*tters/TOPHAT-CTHF138.001
Serving the Pipe Rehabilitation Industry
SUMMARY OF TEST DATA
RESISTANCE OF CIPP TO CHEMICAL REAGENTS
SAMPLE ID:Duration:Date Tested:6/9/2011
Control
Sample
N/A
35.38
0.153
3.89
19735
686175
Test Method
ASTMD
543
543
2122
Mechanical
Property
Observation
Weight
Thickness
Chemical Reagent
(Concentration)
Tap water -pH 6-9
(100%)
Value I %Change
No Change
0.54
0.00
0.00
-0.35
-9.51
35.57
0.153
3.89
19666
620908Max.Flexural
Modulus
No Change
35.54
0.154
3.91
18904
663374
Observation
Weight
Thickness
Nitric Acid
(5%)
Max.Flexural
Modulus
No Change
35.67
0.152
3.86
18685
677818
Observation
Weight
Thickness
Phosphoric Acid
(10%)
Max.Flexural
Modulus
No Change
35.30
0.151
3.83
18577
624416
Observation
Weight
Thickness
Sulfuric Acid
(10%)
Max.Flexural
Modulus
CTHF138.001 Page 1 of 2
HTS
!—Pipe Consultants^
SUMMARY OF TEST DATA
RESISTANCE OF CIPP TO CHEMICAL REAGENTS
SAMPLE ID:Duration:30 Days Date Tested:6/9/2011
Chemical Reagent
(Concentration)
Gasoline
(100%)
Vegetable Oil
(100%)
Detergent
(0.1%)
Soap
(0.1%)
Mechanical
Property
Observation
Weight
Thickness
Max.Flexural
Modulus
Observation
Weight
Thickness
Max.Flexural
Modulus
Observation
Weight
Thickness
Max.Flexural
Modulus
Observation
Weight
Thickness
Max.Flexural
Modulus
Test Method
ASTMD
543
543
2122
790
790
543
543
2122
790
790
543
543
2122
790
790
543
543
2122
790
790
Unit
9
in.
mm.
psi
psi
g
in.
mm.
psi
psi
g
in.
mm.
psi
psi
g
in.
mm.
psi
psi
Control
Sample
N/A
35.47
0.152
3.86
19735
686175
N/A
35.46
0.152
3.86
19735
686175
N/A
34.98
0.153
3.89
19735
686175
N/A
35.50
0.153
3.89
19735
686175
30
Value
Light Brown
35.90
0.152
3.86
17466
583277
No Change
35.49
0.152
3.86
19935
783913
No Change
35.14
0.153
3.89
18884
707161
No Change
35.66
0.153
3.89
19620
731299
Days
%Change
1.21
0.00
0.00
-11.50
-15.00
0.08
0.00
0.00
1.01
14.24
0.46
0.00
0.00
-4.31
3.06
0.45
0.00
0.00
-0.58
6.58
CTHF138.001 Page 2 of 2
HTS Plpo Consultants,Inc.
420 Pickering Street.Houston.TX 77091
www.htsplpeconsultants.com
Phone 713-692-8373
Fax713-692-8S02
Toll Free 1-800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILLV.2.26.
OPERATOR NAME:
E.CARRILLO
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE ID:
CONTROL SAMPLE
SUPPORT SPANTHICKNESS
in)WIDTH
!D
0.502
0.500
0.498 0.148
0.1620.492
0.503
FLEXURAL
MODULUS
si
721154
FLEXURAL
STRENGTH
(BID
MAXIMUM LOAD
(Ibf)STRAIN @ MAX
(In/in)
0.0368
0.0484 637482
772088
0.0470
0.0058StandardDeviation
Minimum 0.0368
0.0500
F138-l-lC.is_flex
——Serving the Pipe Rehabilitation Industry
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
HTS Pipo Consultants,Inc.
420 Pickering Street.Houston.TX 77091
www.htspipeconsultants.com
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26.
OPERATOR NAME:
E.CARRILLO
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE SOAKED IN TAP WATER -pH 6-9 (100%)FOR 30 DAYS
SUPPORT SPAN
(in)THICKNESS
0.494
0.504
FLEXURAL
MODULUS
(PS]
FLEXURAL
STRENGTH
§122311
MAXIMUM LOAD
(Ibf)STRAIN @ MAX
(in/in)
0.0500
0.0500
0.0500
0.0499
0.0001
0.0499StandardDeviation
Minimum 16932
23420
F138-l-lA.is_fIex
Serving the Pipe Rehabilitation Industry
HTS Pipe Consultants,Inc.
420 Pickering Street.Houston,TX 77091
www.htspipeconsultants.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILLV.2.26.
OPERATOR NAME:
E.CARRILLO
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE SOAKED IN NITRIC ACID (5%)FOR 30 DAYS
MAXIMUM LOAD
(Ibf)STRAIN @ MAX
(in/in)
F138-l-2.ls_flex
Serving the Pipe Rehabilitation industry
Phone 713-692-8373
Fax713-692-8S02
Toll Free 1-800-692-TEST
HTS Pipe Consultants,Inc.
420 Pickering Street.Houston.TX 77091
vyww.htspipeconsultants.com
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26.
OPERATOR NAME:
E.CARRILLO
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE SOAKED IN PHOSPHORIC ACID (10%)FOR 30 DAYS
Mean
SUPPORT SPAN
in)
2.5
Standard Deviation
Minimum
Maximum
STRAIN @ MAX
(In/in)
0.0004
0.0492
0.0501
MAXIMUM LOAD
(Ibf)
FLEXURAL
STRENGTH
fpsl)
FLEXURAL
MODULUS
F138-l-3.is_flex
Serving the Pipe Rehabilitation Industry
HTS Pipe Consultants,Inc.
420 Pickering Street,Houston.TX 77091
www.htsplpeconsultants.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26.
OPERATOR NAME:
E.CARRILLO
TEMPERATURE (F)/HUMIDITY (%)
71/50
RATE (in/min)
.066
SOAKED IN SULFURIC ACID (10%)FOR 30 DAYS
SUPPORT SPAN
In)
2.5
THICKNESS
0.153
0.154
FLEXURAL
MODULUSFLEXURAL
STRENGTH
§115727
MAXIMUM LOAD
(Ibf)STRAIN @ MAX
(In/In)600934
697457
613954
620780
0.0004
0.0491StandardDeviation
Minimum
Maximum
F138-l-4.is_flex
Serving the Pipo Rehabilitation industry
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
HTS Plpo Consultants,Inc.
420 Pickering Street.Houston.TX 77091
www.htspipdconsultants.com
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26
OPERATOR NAME:
E.Carrillo
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE ID:
SAMPLE SOAKED IN GASOLINE (100%)FOR 30 DAYS
1
2
3
4_
WIDTH
[in]
0.512
0.506
0.506
0.513
0.492
THICKNESS
flrri
0.141
0.142
0.157
0.159
0.162
SUPPORT SPAN
(Irrt
2.5
2.5
2.5
2.5
2.5
STRAIN @ MAX
(In/in)
MAXIMUM LOAD
(Ibf)
FLEXURAL
STRENGTH
(PSO
FLEXURAL
MODULUS
fpsn
0.0500 59.9 22067
17901
622654
5996980.0500 48.7
0.0501 60.7 18264 547610
54620.0501 54.6 15776
13321
3_
600202
Mean
Standard Deviation
0.0501 45.9
0.0500 54.0
0.0000 6.6
17466
3242
583277
34466
223Minimum0.0500 45.9
0.0501 60.7
13321
22067
5461
622654
F138-l-5.is_flex
Serving the Pipe Rehabilitation Industry
HTS Pipe Consultants,Inc.
420 Pickering Street,Houston,TX 77091
www.htspfpeconsultants.com
Phone 713-692-8373
Fax 713-692-8502
Toll Froo 1-800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26
OPERATOR NAME:
E.Carrillo
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE ID:
SAMPLE SOAKED IN VEGETABLE OIL (100%)FOR 30 DAYS
1
2
3
4
5
WIDTH
(in)
0.498
0.493
0.505
0.503
0.500
THICKNESS
(in)
0.140
0.141
0.154
0.158
0.164
SUPPORT SPAN
(in)
2.5
2.5
2.5
2.5
2.5
1
2
3
4
5
Mean
Standard Deviation
Minimum
Maximum
STRAIN @ MAX
(in/in)
0.0500
0.0500
0.0490
0.0500
0.0500
0.0498
0.0005
0.0490
0.0500
MAXIMUM LOAD
(Ibf)
60.2
54.1
47.6
70.5
71.3
60.7
10.3
47.6
71.3
FLEXURAL
STRENGTH
(psi)
23118 "
20713
14910
21052
19884
19935
3051
14910
23118
FLEXURAL
MODULUS
(PSi)
812218
803326
754441
834958
714620
783913
48615
714620
834958
F138-1-6.IS flex
Serving the Pipe Rehabilitation Industry
HTS PIpo Consultants,Inc.
420 Pickering Street,Houston,TX 77091
www.htspipeconsultants.com
Phono 713-692-8373
Fax 713-692-8502
Toll Froo 1 -800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26
OPERATOR NAME:
E.Carrillo
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE ID:
SAMPLE SOAKED IN DETERGENT (0.1%)FOR 30 DAYS
1
2
3
4
5
WIDTH
(in)
0.512
0.505
0.500
0.502
0.507
THICKNESS
(in)
0.157
0.155
0.153
0.139
0.138
SUPPORT SPAN
(in)
2.5
2.5
2.5
2.5
2.5
1
2
3
4
5
Mean
Standard Deviation
Minimum
Maximum
STRAIN @ MAX
(in/in)
0.0500
0.0500
0.0497
0.0500
0.0500
0.0499
0.0001
0.0497
0.0500
MAXIMUM LOAD
(Ibf)
51.9
69.7
58.8
49.4
50.2
56.0
8.5
49.4
69.7
FLEXURAL
STRENGTH
(DSi)
15431
21555
18844
19087
19502
18884
2207
15431
21555
FLEXURAL
MODULUS
(psi)
673780
717816
697030
728270
718911
707161
21875
673780
728270
F138-1-7JS flex
Serving the Pipe Rehabilitation Industry
HTS Plpo Consultants,Inc.
420 Pickering Street.Houston.TX 77091
www.hlspipeconsullants.com
Phone 713-692-8373
Fax 713-692-8502
Toll Free 1-800-692-TEST
Thursday,June 09,2011
FLEXURAL PROPERTIES OF PLASTICS
ASTM D790
3 POINT BEND
INSTRON CORPORATION
BLUEHILL V.2.26
OPERATOR NAME:
E.Carrillo
TEMPERATURE (F)/HUMIDITY (%)
71 /50
RATE (in/min)
.066
SAMPLE ID:
SAMPLE SOAKED IN SOAP (0.1%)FOR 30 DAYS
WIDTH
iinl
THICKNESS SUPPORT SPAN
(In)
0.495 0.161 2.5
0.497 0.159 2.5
0.502 0.156 2.5
0.500 0.154 2.5
0.507 0.140 2.5
1
2
3
4
5
Mean
Standard Deviation
Minimum
Maximum
STRAIN @ MAX
(In/in)
0.0500
0.0501
0.0499
0.0492
0.0500
0.0499
0.0004
0.0492
0.0501
MAXIMUM LOAD
(Ibf)
73.3
74.5
49.0
55.4
58.0
62.0
11.3
49.0
74.5
FLEXURAL
STRENGTH
(DSi)
21413
22246
15052
17511
21876
19620
3182
15052
22246
FLEXURAL
MODULUS
(DSi)
739851
731545
670115
725982
789000
731299
42351
670115
789000
F138-l-8.is_flex
Serving the Pipe Rehabilitation Industry
BASFAG
Safety data sheet
As per 91/155/EWG
BASF
Pagei of 4
BASF Safety data sheet HV 00187-D/E (D/D)
Date/Revised on:16.05.1995 Version 4
Product:PALATAL*P 921-02
(Date of printing:03.08.1995)
1.Material/Name of the preparation and company
PALATAL*P 921-02
Company:
BASF Aktiengesellschaft
D-67056 Ludwigshafen
Tel.:0621-60-0
Emergency information:
BASF Fire brigade Ludwigshafen
Tel.:0621-60-43333 Fax:0621-60-92664
2.Composition /ingredient details
Chemical characteristics
Unsaturated polyester,dissolved in styrolene
Hazardous ingredients
Styrolene CAS-No.10042-5
Contents:>12.5 Weight %Hazard symbol:Xn
R-Sets:10-20-36/38
3.Possible hazards
Special hazard tips for humans and environment
R-10 -Inflammable
R-20-Harmful if inhaled
R36/38 -Irritates eyes and skin
4.First aid measures
General tips:
On inhaling:
Skin contact
Eye contact:
Swallowing:
Remove contaminated clothes
Rest fresh air,and medical help
Wash thoroughly with water and soap
Rinse eyes (wide open)under flowing water for 15 minutes;
consult an eye specialist
Immediately rinse the mouth and drink pure water,consult a
doctor
5.Fire fighting measures
Suitable fire fighting medium:Foam,dry medium,water,carbon dioxide (C02)
Releases if on fire:Carbon monoxide,carbon dioxide (CO2),water
Special safety gear.None
6.Measures in case of accidental release
Precautionary measures for humans:Respiratory protection necessary
Environmental protection measures:Do not allow flowing into sewerage
Cleaning/picking procedure:Pick up mechanically.Pick up with material sticking
with fluids (e.g.sand,diatomaceous earth,acid binder,universal binder,sawdust)
Page 1 of 4
BASF Safety Information Sheet HV 00187-D/E (D/D)
Date /revised on:16/05/1995 Version 4
Product:PALATAL*P 92 1-02
(Date of printing:03.08.1995)
1.Matorial/Name of the preparation and company
PALATAL*P 92 I -02
Company:
BASF Aktiengesellschaft
D-67056 Ludwigshafen
Tel.:0621-60-0
Emergency information:
BASF Fire brigade Ludwigshafen
Tel.:0621 -60 -43333 Fax:0.621 -60 -92664
2.Composition /ingredient details
Chemical characteristics
Unsaturated polyester,dissolved in styrolene
Hazardous ingredients
Styrolene CAS-No.100-42-5
Contents:> 12.5 Weight %Hazard symbol:Xn
R-Sets:10-20-36/38
3.Possible hazards
Special hazard tips for humans and environment:
R-10 -Inflammable
R-20 -Harmful if inhaled
R36/38 -Irritates eyes and skin
4.First aid measures
General tips:Remove contaminated clothes
On inhaling:Rest,fresh air,and medical help
Skin contact:Hash thoroughly with water and soap
Eye contact:Rinse eyes (wide open)under flowing water for 15 minutes;
consult an eye specialist
Swallowing:Immediately rinse the mouth and drink pure water,consult a
doctor
5.Fire fighting measures
Suitable fire fighting medium:Foam,dry medium,water,carbon dioxide
<C02)
Releases if on fire:Carbon monoxide,carbon dioxide (CO2),water
Special safety gear:None
6.Measures in case of accidental release
Precautionary measures for humans:Respiratory protection necessary
Environmental protection measures:Do not allow flowing into sewerage
Cleaning/picking procedure:Pick up mechanically.Pick up with material
sticking with fluids (e.g.sand,diatomaceous earth,acid binder,
universal binder, sawdust)
Page 2 of 4
BASF Safety Information Sheet HV 00187-D/E {D/D>
Date /revised on:16/05/1995 Version 4
Product:PALATAL*P 92 1-02
7.Handling and storage
Protection against fire and explosion:Keep away from sources of fire -Do not
smoke.Protect the contents from any influence of light.
Storage
Store in a cool,dry place with good air circulation in a well enclosed
condition.Protect from any influence of heat.
S.Bapoouxo restrictions and personal safety gear
Additional instructions for the designing of technical systems
(see 7 )
Components with workplace-related limit values for monitoring
Styrene:
MAR:20 ml/m3 «=85 mg/m3 (Germany)
i
Personal safety gear
Protection while breathing:on exceeding the MAK values (Germany)
Protection for hands:Safety gloves
Protection for eyes:Safety goggles
Protection for body:Body-covering work clothes
General measures for protection and hygiene:Body-covering work clothes,
preventive skin protection using skin protection creams.Avoid contact with
skin,eyes and clothing.
9.Physical and chemical properties
State:liquid
Color/appearance:milky,cloudy
Odor:characteristic (Styrene )
Change of state
Boiling point/boiling range:146 °C (Styrene )
Flashpoint:34 °C {Styrene )
Explosion limits:
-lower 1.1 vol.%
-upper 8.8 vol.%(Styrene )
Ignition temperature:490 °C (Styrene )
Vapor pressure:(Styrene)(20 °C)10 mbar
(50 °C)50 mbar
Density:{20 °C)1.1 g/cm3
Solubility in water:(20 °C)300 mg/1 (approx.)
Solubility in other solvents:Acetone,dichloromethane
pH value:not applicable
viscosity:(23 °C)>300 mPa*3
10.Stability and reactivity
Development of heat during polymerization
11.Toxicologies!information
Acute toxicitv
Styrene:
LD50/oral/rat:5000 mg/kg
LCSU/inhal/rat:11.9 mg/1 / 4 h
Page 3 of 4
BASF Safety Information Sheet HV 00187-D/E (D/D)
Date /revised on:16/05/1995 Version 4
Product:PALATAL*P 92 1-02
12.Ecology-related Information
Information on elimination
Styrene:
Method of experimentation:OECD 301C/ISO 9408/EEC 84/449/V,C.7
Method of analysis:BSB of ThSB
Degree of elimination:>60%
Rating:good biodegradability
Behavior in eco-compartments
No disruption to be expected in the bio-degradation activity of the activated
sludge when moderate concentrations are added into an adapted bio-clarification
plant in an appropriate manner.
Eco-toxic effects
Styrene:
Breathing impediments in the urban activated sludge EC20 100 mg/1 (ISO 8192B/
OECD 210/EEC 88/302 C).
Additional ecological data
Insoluble.The product must not be mixed into watercourses without pretreatment
(through bio-clarificatlon plants).
13.Instructions for disposal
Uncured:
Must be carried out in adherence of the local,official regulations regarding
special treatment,e.g.an appropriate incineration plant.
Cured:
Can be stored away as household waste in adherence of the local regulations,orcanbedispatchedtoanappropriateincinerationplant.
Waste code number for the unused product:55903(Germany)
Non-decontaminated packaging:
Packaging materials,which cannot be decontaminated,must be discarded in a
manner similar to that of the material.Contaminated packaging material must be
completely emptied.They can later be recycled following an appropriatedecontaminationoperation.
14.Information for transportation
Overland transportation
ADR/RID/GGVS/GGVE Class:3 Numeral/letter:31c)
Warning board Hazard code:30 Material code:1866ONcode:-
Marking for the goods:Resin solution (contains Styrene)
Remarks:Not a hazardous freight in containers of up to 450 1
Inland transportation by ship
ADN/ADNR Class:3 Numeral/letter:31c)Marking for the goods:Resin solution (contains Styrene)
Remarks:
Overseas transportation by ship
IMDG/GGVSea Class:3.3 ON code:1866 PG:III
EMS:3-05 MFAG: 310Marinepollutant:yes
Specific technical nomenclature:Resin solution,flammable
(contains Styrene)-marine pollutant
Remarks:
Air transportation
ICAG/IATA Class:3 UN/ID code:1866 PG:IIISpecifictechnicalnomenclature:Resin solution,flammable
(contains Styrene)-marine pollutant
Remarks:
Additional information
Page 4 of 4
BASF Safety Information Sheet HV 00187-D/E (D/D)
Date /revised on:16/05/1995 Version 4
Product:PALATAL*P 92 1-02
15.Regulations
Marking of codes as per ED guidelines
Contains:Styrene
EWG code:202-851-5
Hazard symbol:Xn -Hazardous to health
RIO -Flammable.
RZO -Hazardous to health if inhaled.
R36/38 -Causes irritation to the eyes and skin.
S3 -Store in a cool place.
S37 -Hear appropriate safety gloves.
S51 -Use only inside places with good air-circulation.
National regulations
Classification as per VbF (Germany):unclassified
TA Air(Germany):Class II,point 3.1.7
Water endangerment class:HGK 2(Germany)
16.Miscellaneous information
Vertical lines on the left-hand side margin indicate amendments made to the
previous version.
The information provided herein is as per the current stand of our knowledge
and hence does not present any assurance of the properties.
All entities in receipt of our products are uniquely responsible for adhering
to the prevalent laws and stipulations.
'OWTNSCohning Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics MSDS No.:15-MSD-21555-01-A
* * *Section 1 -Chemical Product and Company Identification * * *
Product Name(s):Woven Unidirectional Fiberglass Fabric (A-Style Warp Unidirectional),Stilchbonded Fiberglass Fabric,
Woven Fiberglass Fabric,Woven Roving
Owens Coming
One Owens Coming Parkway,World Headquarters
Altn.Product Stewardship
Toledo,OH 43659,USA
Emergency Contacts:
Emergencies ONLY (after 5pm ET and weekends):1-419-248-5330,
CHEMTREC (24 hours everyday):1-800-424-9300,
CANUTEC (Canada-24 hours everyday):1-613-996-6666
Health and Technical Contacts:
Health Issues Information (8am-5pm ET):1-800-GET-PINK,
Technical Product Information (8am-5pm ET):1-800-GET-PINK
CAS#
65997-17-3
N/A
N/A
'Section 2 -Composition /Information on Inqredients * *'
Component
Fiber Glass (continuous filament,non-respirable)*
Size
Polyester Yarn
Percent by Wt.
94-100
0-2
0-4"As manufactured continuous filament glass fibers are not respirable.Continuous filament glass products that are
chopped,crushed or severely mechanically processed during manufacturing or use may contain a very small amount
of respirable particulate,some of which may be glass shards.See section 8 of Material Safety Data Sheet for
exposure limit data.
Component Related Regulatory Information
This product may be regulated,have exposure limits or other information identified as the following:glass wool
fiber,fibrous glass and nuisance particulates.
Component information/Information on Non-Hazardous Components
No additional information available.
I * * *Section 3 -Hazards Identification * * *
Emergency Overview
No unusual conditions are expected from this product.
Appearance and Odor:White/off-white colored solid with no odor.
Primary Route(s)of Exposure:Inhalation,lungs,skin and eye
Page 1 of 8 Issue Date:06/05/03 North American-English
/OWCNSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics
Potential Acute Health Effects
MSDS No.:15-MSD-21555-01
Inhalation:
Dusts and fibers from this product may cause mechanical irritation of the nose,throat and respiratory tract.
Skin Contact:
Dusts and fibers from this product may cause temporary mechanical irritation to the skin.
Eye Contact:
Dusts and fibers from this product may cause temporary mechnical irritation to the eyes.
Ingestion:
Ingestion of this product is unlikely.However,ingestion of product may produce gastrointestinal irritation and
disturbances.
Medical Conditions Aggravated by Exposure:
Chronic respiratory or skin conditions may temporarily worsen from exposure to this product.
Chronic Conditions:
See Section 11 for additional information.
Section 4 -First Aid Measures * * *
Inhalation:
If inhaled,move the affected person to fresh air.If irritation persists get medical attention-
Skin Contact:
For skin contact,wash with mild soap and cold water.Do not wash with warm water because this will open up the
pores of the skin,which will cause further penetration of the fibers.Use a washcloth to help remove fibers.To
avoid further irritation,do not rub or scratch affected areas.Rubbing or scratching may force fibers into the skin.
If irritation persists get medical attention.
Never use compressed air to remove fibers from the skin.If fibers are seen penetrating from the skin,the fibers
can be removed by applying and removing adhesive tape so that the fibers adhere to the tape and are pulled out
of the skin.
Eye Contact:
Immediately flush eyes with plenty of running water for at (east 15 minutes.If irritation persists get medical
attention.
Ingestion:
Ingestion of this material is unlikely.If it does occur,watch the person for several days to make sure that partial
or complete intestinal obstruction does not occur.Do not induce vomiting unless directed to do so by medical
personnel.Seek medical attention if irritation persists.
Page 2 of 8 Issue Date:06/05/03 North American -English
'OWENSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics MSDS No.:15-MSD-21555-01
I "*Section 5 -Fire Fighting Measures * * *|
Flash Point:None Flash Point Method:Not determined
Upper Flammability Limit:None Lower Flammability Limit:None
Flammability Classification:Non-flammable
Extinguishing Media:
Dry chemical,foam,carbon dioxide,and water fog.
Unusual Fire &Explosion Hazards:
None known.
Fire-Fighting Instructions:
Use self-contained breathing apparatus (SCBA)and full bunker turnout gear in a sustained fire.
Hazardous Combustion Products:
Primary combustion products are carbon monoxide,hydrogen,carbon dioxide and water Other undetermined
compounds could be released in small quantities.
I ***Section 6-Accidental Release Measures ***
Containment Procedures:
This material will settle out of air.If concentrated on land,it can then be scooped up for disposal as non-
hazardous waste.This material will sink and disperse along the bottom of waterways and ponds-It cannot easilyberemovedafteritiswaterbome;however,the material is non-hazardous in water.
Clean-Up Procedures:
Scoop up material and put into a suitable container for disposal as a non-hazardous waste.
* **Section 7 ■Handling and Storage ** *
Handling Procedures:
Keep product in its packaging,as long as practicable to minimize potential dust generation.Keep work areasclean.Avoid unnecessary handling of scrap materials.Wear PPE as described in Section 8.
I * * *Section 8 -Exposure Controls /Personal Protection * * *
Exposure Guidelines:
A:General Product Information
Follow all applicable exposure limits.
Page 3 of 8 Issue Date:06/05/03 North American -English
'OWENSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics
B:Exposure Limits
Fiber Glass Continuous Filament (65997-17-3)
Ingredient OSHA PEL
(8-hr TWA)
Non-respirable fibers and particulate 15 mg/m3 (total dust)(a)
Respirable particulate 5 mg/m {respirable dust)(b)
Respirable particulate with fiber like
dimensions (glass shards)None Established
MSDS No.:15-MSD-21555-01
ACGIHTLV
(8-hr TWA)5 mg/m3 (inhalable fraction)
None
None Established
Polyester Yarn OSHA PEL
(8-hr TWA)15 mg/m3 (total dust)
5 mg/m (respirable dust)
ACGIH TLV
(8-hr TWA)
10 mg/m (inhalable fraction)3 mg/m3 (respirable)
Ventilation:
General dilution ventilation and/or local exhaust ventilation should be provided as necessary to maintain
exposures below regulatory limits.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection:
A properly fitted NIOSH approved N 95 series disposable dust respirator such as the 3M model 8210 (model 8271
in high humidity environments)or equivalent should be used when high dust levels are encountered,the level of
glass fibers in the air exceeds the occupational exposure limits,or if irritation occurs.
Skin Protection:
Normal work clothing (long sleeved shirts and long pants)is recommended. Use gloves.Skin irritation is known to
occur chiefly at the pressure points such as around the neck,wrists,waist and between the fingers.
Eyes/Face Protective Equipment:
Wear safety glasses,goggles or face shield.
* * *Section 9 -Physical &Chemical Properties
Appearance:
Physical State:
Vapor Pressure (mm Hg @ 20 C):
Boiling Point:
Specific Gravity (Water=1):
Evaporation Rate (n-Butyt
Acetate=1):
VOC:
White/off-white Solid
Solid
Not applicable
Not applicable
2.60
Not applicable
<0.4%
Odor:
pH:
Vapor Density
(Air=1):
Solubility (H2O):
Freezing Point:
Viscosity:
None
Not applicable
Not applicable
Insoluble
Not applicable
Not applicable
Melting Point:>800°C
Physical Properties:Additional Information
No additional information available.
Page 4 of 8 Issue Date:06/05/03 North American -English
'OWTNSCorniNn
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics MSDS No.:15-MSD-21555-01
* * *Section 10 -Chemical Stability &Reactivity Information * * *|
Stability:
This is a stable material.
Conditions to Avoid:
None known.
Incompatible Materials:
None known.
Hazardous Decomposition Products:
Sizing or binders may decompose in a fire.See Section 5 of MSDS for information on hazardous combustion
products.
Hazardous Polymerization:
Will not occur.
* * *Section 11 -Toxicotogical Information * * *^^i ~^ZH~
Acute Effects:
General Product Information
Dusts may cause mechanical irritation to eyes and skin.Ingestion may cause transient irritation of throat,
stomach and gastrointestinal tract.Inhalation may cause coughing,nose and throat irritation,and sneezing.
People with pre-existing respiratory conditions,may experience difficulty breathing,congestion and chest
tightnes.
Carcinogenicity:
Fiber Glass Continuous Filament:The International Agency for Research on Cancer (IARC)in June, 1987.categorized
fiber glass continuous filament as not classifiable with respect to human carcinogenicity (Group 3).The evidence from
human as well as animal studies was evaluated by IARC as insufficient to classify fiber glass continuous filament as a
possible,probable,or confirmed cancer causing material.
The American Conference of Governmental Industrial Hygienists (ACGIH)A4 classification,not classifiable as a human
carcinogen,for respirable continuous filament glass fibers is based on inadequate data in terms of its carcinogenicity inhumansand/or animals.
For respirable continuous filament glass fibers,a TLV-TWA of 1 fiber/cc was adopted to protect workers against
mechanical irritation.The TLV-TWA of 5 mg/m3 was adopted for nonrespirable glass filament fiber,measured as
inhalable dust,to prevent mechanical irritation of the upper respiratory tract.
Note:There are no known chronic health effects connected with long term use or contact with these products.
Products that are chopped,crushed or severely mechanically processed during manufacture or use may contain a very
small amount of respirable glass fiber-like fragments.NIOSH defines "respirable fibers "as greater than 5 microns in
length and less than 3 microns in diameter with an aspect ratio of >5:1 (length-to-width ratio).
Chronic Study in Animals
A laboratory test was conducted with a different product (special application glass fiber)with comparable composition and
durability.Test animals breathing very high concentrations of respirable fibers on a long-term basis developed fibrosis
lung cancer and mesothelioma.
Page 5 of 8 Issue Date:06/05/03 North American-English
'OWENSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics MSDS No.:15.MSD.21555-01
H alS (n=?32exP°sed t0 1022 f/ccfor 5 h^ay,7 days/week for 52 weeks developed lung tumorsandcardnoma)C'n°m ^^(}°f ^unexP0Sed contro1 9rouP <n=38)developed lung tumors (adenoma
Five percent (5%)of the rats in the exposed group developed mesothelioma and 12.5%developed advanced fibrosrsNoneoftheratsintheunexposedcontrolgroupdevelopedmesotheliomaand0.6 %developed advanced fibrosis.
A second group of rats was exposed to a similar concentration of asbestos (respirable amosite fibers)for 5 hours/dav 7
th?QraeRSL"1-thfl-IS Simi'ar diS6ase rateS for lhe sPecial aPPli^tion fiber and amosite asbestos,had beenwhichSidl.r2£ESSPaPer (lnha''T°X-8:323-343-1 "6 re°-That Paper specifical|y slaled lha ln rals all fiberswhichweredurableenoughtoremaininaratlungfortwo(2)years or more would produce the same disease rates if theZTnTZZluna5t^W^PPfcafiOn ^5 mUCh '6SS dUrable than aSbeslOS'"**2S eS^to™n^J5 J^9 ?^the ^°(2)year "me period'Ttle results of lhe current study are therefore notexposedte^ihese nbers '''Simi'ar diS6aSe rateS W0L"d be Seen '"'°nger "Ved sPecies or humans
B:Component Carcinogenicity
Fiber Glass (Continous Filament)(65997-17-3)
ACGIH:A4 -Not classifiable as a human carcinogen.
IARC:Group 3 "not classifiable as to its carcinogenicity to humans"
June 1987 meeting,October 2001 meeting
* * *Section 12 -Ecological Information
No data available for this product.This product is not anticipated to harm animals,plants or fish.
* * *Section 13 -Disposal Considerations
itiUSEPAWasteNumber&Descriptions:
A:General Product Information
Material,if discarded,is not expected to be a characteristic hazardous waste under RCRA.
B:Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions:
Dispose of waste material according to Local,State,Federal,and Provincial Environmental Regulations.
Section 14 -Transportation Information * *
US DOT Information
Shipping Name:Not regulated for transport.
Hazard Class:None
UN/NA #:None
Packing Group:None
Required Label(s):None
PaQe 6 of 8 Issue Date:06/05/03~North American -English
'OWENSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics
TDG Information
Shipping Name:Not regulated for transport.
Hazard Class:None
UN/NA#:None
Packing Group:None
Required Label(s):None
Additional Info.:None
Additional Transportation Regulations:
No additional information available.
MSDS No.:15-MSD-21555-01
Section 15 -Regulatory Information
US Federal Regulations:
A:General Product Information
No additional information available.
B:Component Analysis
No additional information available.
The following is provided to aide in the prepartion of SARA 311 and 312 reports.
SARA 311/312
Acute Health Hazard:Yes
Chronic Health Hazard:No
Fire Hazard:No
Sudden Release of Pressure Hazard:No
Reactive Hazard:No
C:Clean Air Act
The following components appear on the Clean Air Act-1990 Hazardous Air Pollutants List-
None
State Regulations:
A:General Product Information
No additional information available.
B:Component Analysis -State
The following components appear on one or more of the following state hazardous substances lists:
Component
Fiber Glass (continuous filament)65997-17-3
CA
No
FL
No
MA
No
MN
No No
PA
No
Other Regulations:
A:General Product Information
No additional information available.
Page 7 of 8 Issue Date:06/05/03 North American -English
'OWENSCorning
Material Safety Data Sheet
Material Name:Woven Rovings and Fabrics
B:Component Analysis -Inventory
MSDS No.:15-MSD-21555-01
Component
Fiber Glass (Continuous Filament)
CASS
65997-17-3
TSCA
Yes
DSL
Yes
EINECS
Yes
C:Component Analysis -WHMIS 1DL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List-
None
WHMIS Status:Not controlled
WHMIS Classification:None
***Section 16-Other Information ***
HMIS and NFPA Hazard Ratinqs:Cateqory
Acute Health
Flammability
Reactivity
HMIS
1
0
0
NFPA
1
0
0
NFPA Unusual Hazards:None
HMIS Personal Protection:To be supplied by user depending upon use.
Reasonable care has been taken in the preparation of this information,but the manufacturer makes no warranty
of merchantability or any other warranty,expressed or implied,with respect to this information.The manufacturer
makes no representations and assumes no liability for any direci,incidental or consequential damages resultingfromitsuse.
Revision Summary:
This is a revised MSDS,which replaces 15-MSD-21555-01 with updated product names and new formattingReadthisinformationcarefully.
Get OC MSDS electronically via Internet:http://www.owenscorninq.com or by calling 1-800-GET-PINK.
This is the end of MSDS #15-MSD-21555-01-A
Page 8 of 8 Issue Date:06/05/03 North American -English
Material Safety Data Sheet
According to 91/155 EC
Printing date 15.12.2000
Page 1/5
Reviewed on 15.12.2000
I iilfiiiificiiriiiii ofsubstance:
Product details:
Trnile name:Paste 035671.SI Kp.:A
■Manufacturer/Supplier:
Cosmic -Sondermaschinenbau GmbH
A-5072 Kasten.Slcinabruck35
Tel:1)0-13-(0)2?'44/7004.Fax DW 9
-Further information obtainablefrom:technical department,phone 0045/2144-7004-N
■Information in case ofemergency:Tarirt information centre Tel.+H 43/(0)1-406 43 43
2 Composition/Data on components:
■Chemical characterization
■Description:Mixture ofsubstances listed below with nonhazardous additives.
Dangerous components:
Modi/.Bisphenol-A epoxy resin.M0<700
H-W:36/38-43
2.3-111%
modi/.bisphenol-A epoxy resin with reactive thinner,MG<=700MXn:20.21-36/38-43 '
modif.bisphenoie-A epichlorhydrme resin with rvactive thinner,MG <~700
P-\7;J(i 38-43
2.3-1(1%
2.5-10%
3 Hazard identification
Hazard description:
Xi Irritant
■Information concerning to particular hazards to man and environment
R 36'38 Irritating to eyes and skin.
H 43 May cause senslttzation by skin contact.
Contains epoxy constituents.See information supplied by the manufacturer.
■Classification system
The classification is according to the latest editions ofthe EU-lists.and extended by company
and literature data.
4 First aid measures
■General information
Immediately remove any clothing soiled by the product.
Avoid contact with eyes andskin.
■After skin contact Immediately wash with water and soap and rinse thoroughly.
■After eye contact
Rinse opened eyefor at least 15 minutes under running water.Tlien consult a doctor.
-After swallowing
Rinse out mouth and then drink plenty ofwater.
Callfor a doctor immediately.
S Firefighting measures
Suitable extinguishing agents Foam,powder,carbon dioxide,water spray
■For safety reasons unsuitable extinguishing agents Water withfulljet.
(Could,on page 2)
en
Material Safety Data Sheet
According to 91/155 EC
Printing dale 15.12.2000
rage 2/5
Reviewed on 15.12.2000
Trade name:Paste 03567 LSI Kp.:A
(Gnitd.ofpage I)■Special hazards caused by the substance,its products of'combustion or resulting gases:
Formation oftoxic gases is possible during healing or in cast:offire.
■Protective equipment:
Wear self-contained respiratory protective device.
Do not inhale smoke.
■A dditional information
Collect contaminatedfsrefighting water separately.It must not enter the sewage system.
6 Accidental release measures
■Person-related safely precautions;Wear protective clothing.
■Measuresfor environmentalprotection:
Do not allow product to reach sewage system or any water course.
■Measuresfor cleaning/collecting:
Pick up mechanically.
Dispose ofthe material according to regulations.
7 Handling and storage
■Handling
•Informationfur safe handling:
The usual precautionary measures arc to be adheredto when handling chemicals.
■Information about protection againstfires and explosions:,\'o special measures required.
■Storage
■Requirements to be met by storerooms and receptacles:
Store container tightly shut in a dry place wilh good ventilation.
■Information about storage in one common storagefacility:
Keep awayfrom strong acidic and alkaline Material andfrom Oxidants.
■Further information about storage conditions: Protectfromfrost.
S Exposure controls and personalprotection gear
■Additional information about design oftechnicalfacilities:Nofurther data;see item 7.
■Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities ofmaterials with critical values that have
to be monitored at the workplace.
■Additional information:Vic lists valid during the making were used as basis.
•Personalprotective equipment
•Generalprotective and hygienic measures
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end ofwork.
Avoid contact with the eyes and skin.
■Protection ofhands:Rubber gloves
■Eyeprotection:Tightly sealedgoggles.
■Body protection: Protective work clothing.
')Physical and chemical properties:
Form:
Colour:
Pasty
Light grey
(Could,on page 3)
GB
Material Safety Data Sheet
According to 91/155 EC
Printing dale 15.12.2000
Page 3/5
Reviewed on 15.12.2000
Trade name:Paste 03567 LSI Kp.:A
•Odour:
•Change in condition
Meltingpaint/Melting range:
Bailing point/Boiling range:
-Flash point:
■Self-igniting:
■Danger ofexplosion:
■Density at 20°C:
■Solubility in /Miscihitity with
Water:
(Guild of page 2)
Characteristic
undetermined .
200°C
Not applicable
Product is not selftgniting.
Product does notpresent an explosion hazard.
l.Jglcm1
Dilutable with water.
Hi Stability andreactivity
Tltermal decomposition/conditions to be avoided:
No decomposition ifused according to specifications.
■Materials to be avoided:Concentrated acides.bases andstrong oxidating substances.
■Dangerous reactions Exothermic reaction with axidants.strong acides and alkalincs.
■Dangerous decomposition products:
In case offire or thermal decomposition passibleformation of carbon and nitric oxides aa well
as toxicgases andfumes.
■Additional information:
The mixture ofthe components heats up when standing (heat ofreaction).When usedproperly
the heat is derived to the ground.
11 toxtcological information
•Acute toxlclty:
Primary irritant effect:
■on the skin:Irritant to skin and mucous membranes.
■on the eye:Irritating effect.
■Sensitization:Sensitization possible by skin contact.
Additional toxicofogical information:Irritant
12 Ecological information:
Generalnotes:
Water hazard class 2 (German Regulation)(Self-assessment):hazardousfor water.
Do not allow product to reach ground water,water course or sewage system.
13 Disposal considerations
Product:
■Recommendation
Disposal in accordance with national and local laws and by-laws.
Must not be disposed together with household garbage.Do not allowproduct to reach sewage
svstem.
(ConT[I on page t)
Material Safety Data Sheet
According to 91/155 EC
Priming date 15.12.2000
Page 4/5
Reviewed on 15.12.2000
Trade name:Paste 035671.51 Kp.:A
(Cbntd.of payc i)
Waste disposal key:
Mix both components to harden the material and dispose ofil as OS 04 04 (EG waste disposal
key).
■European waste catalogue
Wastes from the manufacture, formulation,supply and use fAIi-'SU)of coatings,
/paints,varnishes and vitreous enamels), adhesive,sealants anil printing inks
wastesfrom MFSU ofadhesives andsealants (Including waterproofing products)
adhesives and sealants sludgesfree ofhalogenated solvents
OS 00 III)
08 04 00
OH 04 06
OS 00 DO
08 04 00
08 04 04
Wastes Jrom the manufacture,Jormiilalion,supply and use (MI-SI!)of coalings,
(paints,varnishes and vitreous enamels), adhesive,sealants andprinting inks
wastesfrom t\fFSt!ofadhesives and sealants (including waterproofing products)
hardened adhesives and sealants
Uncleanedpackaging:
Recommendation:Disposal according to official regulations.
14 transport information 1
•Landtransport ADR/RID (cross-border)
..III..
ADR/RID class:
•Item:
•Danger code (Kemler)
•UN-Number:
■Label
■Description ofgoods:
9 Miscellaneous dangerous substances and articles.
lie
■90
3082
9
Environmentally hazardous substance,liquid,n.o.s.,modif.
Bisphenol A-epoxy resin MG<700
■Maritime transport 1MDG:
A\\h
\tV
■1MDG Class:
■Page:
■UN Number:
■Packaging group:
■Marine pollutant:
■Proper shipping name
9
9028
3082
111
No
:Environmentally hazardous substance,liquid,n.o.s.,modif.Bisphenol
A-epoxy resin;MG<700
•Airtransport ICAO-TI and IATA-DGR:
..III,.
■ICAO/IATA Class:
UN/ID Number:
9
3082
(Conld.on page i)
GH
Material Safety Data Sheet
According to 91/155 EC
Printing date 15-12.2000
Page 5/5
Reviewed on 15.12.2000
Trade name:Paste 03567 LSI Kp.:A
(Contd.oFpn£c -I)
■Packaging group:III
■Proper skipping name:Environmentally hazardous substance,liquid,n.o.s,,modif.Bisphenol
A-epnxy resin;MG<700
15 Regulations
Labelling according to EUguidelines:
Hie product has been classified and marked in accordance with EU Directives I Ordinance on
Harardoits Materials
Code letter and hazard designation ofproduct:
XI Irritant
Hazard-determining components oflabelling:
modif.hisphenol-A epoxy resin with reactive thinner,MG<=7QQ
Modif.Bisphenol-A epoxy resin.MG<700
modif.bisphenole-A epichlorhydrine resin with reactive thinner,MG <=700
Risk phrases:
36/38 Irritating to eyes andskin.
43 May cause sensiti:ation by skin contact.
Safety phrases:
24 Avoid contact with skin.
26 In caxe of contact with eyes,rinse immediately with plenty of water and seek medical
advice.
37/39 Wear suitable gloves and eye/face protection.
60 Wtis material and its container must be disposed ofas hazardous waste.
■Special labelling ofcertain preparations:
Contains epoxy constituents.See information supplied by the manufacturer.
■National regulations
■Waterhazard class:Water hazard class 2 (Self-assessment):hazardousfor water.
16 Other information.
This information is based on our present knowledge.However,this shall nor constitute a
guarantee for any specific productfeatures and shall not establish a legally valid contractual
relationship.
Marked "'"chapters have been changed.
-Department issuing MSDS:technical department
■Contact:
Tel.-No.:++43/(0)2744/7004
Fax.-No.:+',43/(0)2744/7004-9
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.06.2002
Page I 5
Reviewed on 28.05.2002
I Identification ofsubstance:
Product details:
Trade name:Paste 03S67LSI Kp.:B
Manufacturer/Supplier:
Cosmic -Sondermaschinenbau GmbH
A-3072 Kasten.Steinabruck 35
Tel:0O43-(0)2744/7ttO4,Fax D\V9
Further information obtainablefrom:technical department,phone 0043/2744-7004'14
Information in case ofemergency:Toxin information centre:Tel.++43/(0)1-406 43 43
2 Composition/Data on components:
Chemical characterization
■Description:Mixture ofsubstances listed below with nonhazardous additives.
Dangerous components:
Modified aliphatic pulyiimine I C;R 22-34-43-52/53 10-25%
3 Hazard identification
Hazard description:
C Corrosive
Information concerning toparticular hazards to man and environment
R 34 Causes burns.
R 43 May cause sensitisation by skin contact.
Classification system
The classification is according to the Idlest editions ofthe EU-listS,and extended by company and
literature data.
4 First aid measures
General information
Avoid contact with eyes and skin.
immediately remove tiny clothing soiled by the product.
After inhalation
Supplyfresh air and callfor a doctor.
In case ofunconsciousness placepatient stably in side positionfor transportation.
After skin contact Immediately wash with water andsoap and rinse thoroughly.
After eye contact
Rinse opened eye for at least 15 minutes under running water.Then consult a doctor.
■After swallowing
Rinse out mouth and then drink plenty ofwater.
Drink plenty ofwater andprovide fresh air.Callfor a doctor immediately.
5 Firefighting measures
Suitable extinguishing agents
Foam,powder,carbon dioxide,water spray
Usefire extinguishing methods suitable to surrounding conditions.
Special hazards caused by the substance,itsproducts ofcombustion or resulting gases:
Formation oftoxic gases is possible during heating or in case offire.
Protective equipment:
Wear self-contained respiratory protective device.
Do not inhale smoke.
(C'omd on page 2)
—GB-
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.06.2002
Page 2/5
Reviewed on 28.05.2002
Trade name:Paste 03567LS1 Kp.:B
(Cortd.ofpage 1)
■Additional information
Collect contaminatedfirefighting water separately.It mittf not enter the sewage system.
6 Accidental release measures
■Person-related safety precautions:Wear protective equipment.Keep unprotected persons away.
■Measuresfor environmental protection:Do not allow to enter sewers/surface or ground water.
Measuresfor cleaning/collecting:
Dispose ofthe material according lo regulations.
Absorb with liquid-binding material (sand,dialomite.acid binders,universal binders;sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
11iiniiling
Information forsafe handling:
The usualprecautionary measures are to be adhered to when handling chemicals.
Infarnuition aboutprotection againstfires ami explosions:No special measures required
Storage
Requirements to be met by storerooms and receptacles:
Store container tightly shut in a dryplace with good ventilation.
Obsen-e customary regulationsfor storage according lo the water hazardous class.
Information about storage in one common storagefacility:
Keep awayfrom strong acidic and alkaline Material andfrom Oxidants.
Further information about storage conditions:Keep receptacle tightly sealed.
Storage class
Storage class 8 (YCl-concept):Corrosive matter
Storage class 12 (VCl-conceptj:Incombustible liquid
Class according to regulation onflammable liquids:Void
H kxposttre controls and personalprotection gear
Additional information about design oftechnicalfacilities:Nofarther data:see item 7.
Ingredients with limit values that require monitoring at the workplace:
The product does nal contain any relevant quantities ofmaterials with critical values that have to
be monitored at the workplace.
Additional information:The lists valid during the making were used as basis.
Personalprotective equipment
General protective find hygienic measures
Keep awayfrom foodstuffs,beverages andfeed.
Immediately remove all soiled and contaminatedclothing
Wash hands before breaks and at the end ofwork.
Avoid contact with the eyes andskin.
Respiratory protection:Not necessary ifroom is well-ventilated.
Protection ofhands:
Rubber gloves
Protective gloves.
Eye protection:Tightly sealedgoggles.
|Contd on page 3)
Material Safety Data Sheet
According to 91/155 EC
Priming date 17.06.2002
Page 3/5
Reviewed on 28.05.2002
Trade name:Paste 03567L51 Kp.:B
Body protection:Protective work clothing.
[Conlii.ofpage2)
9 Physical ami chemical properties:
■Form:
■Colour:
Odour:
-Change in condition
Melting point/Melting range
Boiling point/Boiling range:
■Flash point:
■Ignition temperature:
-Self-igniting:
Danger ofexplosion:
■Vapour pressure at 20°C:
■Density at 20°C:
■Solubility In /Miscibility with
Water:
■Solvent content:
Organic solvents:
■Solids content:
Pasty
Black
Characteristic
Undetermined
200"C
INBC
35l)aC
Product is not selfigniting.
Product does not present an explosion hazard.
OhPa
}.7g/cm>
Partly miscihle
0.0%
80.0 %
10 Stability ami reactivity
Thermal decomposition /conditions to be avoided:
No decomposition ifused according to specifications.
Materials to be avoided:Concentrated acid1:,bases and strong oxidating substances.
Dangerous reactions Exothermic reaction with oxidants,strong acides and alkalines.
Dangerous decomposition products;
In case offire or thermal decomposition possibleformation ofcarbon and nitric oxides as well as
toxic gases andfumes.
Additional information:
The mixture ofthe components heats up when standing (heat ofreaction).When used properly the
heat is derived to the ground.
11 Toxicolouical information
Acute toxicity:
■LD/LC50 values relevantfor classification:
Modified aliphatic piilyamine
Oral LD50 910 ing,kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin andmucous membranes.
on the eye:Strong caustic effect.
Sensitization:Sensitization possible by skin contact.
Additional loxicological Information:
Corrosive
(Could onpage4)
(jit -
Material Safety Data Sheet
According to 91/155 EC
Priming date 17.06.2002
Page 4/5
Reviewed on 28.05.2002
Trade name:Paste 03567L5I Kp.:B
(Co«d.ofpagc3)
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger ofperforation
ofesophagus and stomach.
The product shows the following dangers according to the calculalion method ofthe General EU
Classification Guidelinesfor Preparations as issued in the latest version:
12 Ecological information;
General notes:
Water hazard class 2 (German Regulation)(Self-assessment):hazardousfor water.
Do nol allow product to reach ground water,water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Danger to drinking water ifeven small quantities leak into the ground.
IJ Disposal cimsitlenifions
Product:
Recommendation
Disposal in accordance with national and local laws and by-laws.
Must not be disposed together with household garbage.Do not allow product to reach sewage
system.
Uncleanedpackaging:
Recommendation;Disposal according to official regulations.
Recommended cleansing agents:Water,ifnecessary together with cleansing agents.
14 Transport information
Land transport ADR/RID (cross-border)
ADR/RID class:8 Corrosive substances.
Item:53c
Danger code (Kemler):HO
UN-Number:2327
Label 8
Description ofgoods:Trimethylhe.xamelhylenediamines.mixture
Maritime transport IMDG:
8
8243
2327
III
8-05
320
No
IMDG Class:
Page:
UN Number:
Packaging group:
EMS Number:
MFAG:
Marine pollutant:
(Ccmul on page 5|
—Gil-
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.06.2002
Page 5/5
Reviewed on 2fi.05.2002
Trade name:Paste 03567L51 Kp.:B
(Conld o
Proper shipping mime:Trimethylhexamelltylencdiamines.mixture
Air transport ICAO-TI and IATA-DGR:
Ah-
1CA0/IATA Class:8
■UN/ID Number:2327
Packaging group:ill
Proper shipping name:Triinetliylhexamelhylencdiamines,mixture
15 Regulations
Labelling according to EUguidelines:
The product has been classified and marked in accordance with EU Directives /Ordinance on
Hazardous Materials
Code letter and hazard designation ofproduct:
C Corrosive
Hazard-determining components oflabelling:
Modified aliphatic polyamine
Risk phrases:
34 Causes burns.
43 May cause sensilisation by skin contact.
Safetyphrases:
1/2 Keep locked up and out ofthe reach ofchildren,
13 Keep awayfrom food, drink mid animalfeedingstuffs.
26 In case ofcontact with eyes,rinse immediately with plenty of miter and seek medical
advice.
29/56 Do not empty into drains,dispose of this material and its container at hazardous or
special waste collection point.
36/37/39 Wear suitable protective clothing,gloves and eye/face protection.
45 In case ofaccident or ifyou feel unwell,seek medical advice immediately (show the label
where possible).
National regulations
Classification according to VbF:Void
Waterhazard class:Water hazard class 2 (Self-assessment):hazardousfor water.
16 Other infonntitioti:
This information is basedon our present knowledge.However,this shall not constitute a guarantee
for any specific productfeatures and shall mil establish a legally valid contractual relationship.
Marked "'"chapters have been changed.
-Department issuing MSDS:technical department
Contact:
Tel-No,:++43/(0)2744/7004-14
Fax.-No.:++43/(0)2744/7004-9
ENGINEERING OFFICE FOR PLASTICS TECHNOLOGY
ROLF SIEBERT
APPLICATION TECHNOLOGY
QUALITY ASSURANCE
MATERIALS TESTING
Expert for application and testing of reinforced plastics
and thermosetting materials for sewage and waste
disposal systems publicly appointed and sworn in by the
Chamber of Industry and Commerce,LObeck
SchulstraBe 22
22 113 Oststeinbek /Hamburg
phone +49 (40)73 91 41
fax +49 (40)739 42 77
Expert's Report
report no.:SVB 97.20471 S
UP-GF resin mats for the manufacture of GFRP short liners and hoods for the
repair of partial damages in sewers and sewage pipelines
Material analyses and component tests
commissioned by:
Cosmic
Johann Kubel
Steinabruck 35
A-3072Kasten
Austria
Contents:
1.Basic material -technical basics
2.Material properties
3.Component tests
4.Conclusion
This report includes 7 pages (incl.cover)and 2 enclosures and must not by copied without the
written consent of the expert
ing.-bOro
rolf siebert
rst 040/739141
OSH 040/7394277
GFRP shortliners and hoods
materials and component testing
pagei
report no.:
SVB 97.20471 S
1.Basic material -technical basics
Short liners developed for partial damage repair are not designed as prefabricated hose
liners ready to be fitted,but they are cut up on the construction site from a GF-UP matted
laminate,impregnated and physically thickened by the factory,according to the require
ments of each measure (cf.expert's opinion report no.:SVB 97.00470 S).
An unsaturated polyester resin -basis:isophthalic acid neopentyl glycol -(resin group 3
according to DIN 18 820 part 1)with moulding material properties of type 1140 (DIN
16 946 part 2)is used as resin matrix,a textile glass matted laminate (DIN 61 850 ff.)-
basis:E-CR-glass -serves as reinforcing material.
Hardening takes place after installation by means of ultraviolet light.
The manufacture and conduction of the tests required for quality assurance takes place
according to the following standards and directives:
leaflet ATV-M 143,
part 1-3
inspection,repair,rehabilitation and renewal of
sewers and sewage pipelines
work sheet ATV-A 127-2 static calculations of drainage sewers and
pipelines
DIN 18 820,part 1 to 3
DIN EN 1228
DIN EN ISO 761
DIN EN ISO 178
DIN EN ISO527-4
DIN EN ISO 1172
DIN 53 769,part 1
DIN 53 397
DIN EN ISO 175
DIN 53 476
DIN 53 495
DIN 16 945
laminate made of polyester resins reinforced by
textile glass fibre for load-bearing components;
assembly,manufacture,properties
long-term /short-term vertical crushing test on
pipes
bending test (3-point method)
testing of bending strength and deformation
properties
determination of bending Young's modulus
tensile test
testing of tensile strength
determination of annealing loss
verification of composition of
GFRP-laminates
determination of inter-laminar tensile strength
resistance to chemical attack
resistance to liquids
determination of water uptake
reactive resins,reactive agents and reactive resin
ing.-bOro
rolf siebeht
□E)040/739141
040/7394277
GFRP shortliners and hoods
materials and component testing
page 2
report no.:
SVB 97.20471 S
DIN 16 946,part 2
masses
testing method
resin moulding materials,types
DIN 61 850 -DIN 61 855 textile glass
terms,technical conditions of delivery
textile glass mats,textile glass fabric
DIN 50 049
2.Material properties
textile glass rovings
certificates for material tests
After successful compaction and hardening by means of ultraviolet light,attainable
characteristic values of the material were determined for the UP resin mats impregnated
and ready to be used for the production of short liners and hoods.
Depending on the glass content and degree of area compaction,the mechanical
performance corresponds to that of a normal laminate (matted laminate)according to
GFRP application standard DIN 18 820 part 2.
Table of characteristic values for moulding material
test
bending strength abB
bending Young's
modulus Eb
tensile strength od
glass content iy
wall thickness
standard
DIN EN ISO 178
DIN EN ISO 178
DIN EN ISO 527-4
DIN EN ISO 1172
unit
N/mm2
N/mm2
N/mm2
%
mm
value
156-195
6.000-11.000
100-156
30-49
3-6
Since material-specific data depends on the particular glass content,which itself is
influenced by the application pressure occurring during installation,we recommend with a
view to application in damaged pipelines to use mainly the lower values as basis for static
evidence.
After hardening by means of ultraviolet light the GF-UP moulding material can
immediately take mechanical load and is chemically resistant to municipal sewage
(pH 1-10),further post-hardening is not necessary.
ing.-bOro
rolfsiebert
QD 040/739141
ffigffl 040/7394277
GFRP shortliners and hoods
materials and component testing
page 3
report no.:
SVB 97.20471 S
3.Component tests
Short liners produced during field tests and fitted into pipelines DN 250 were examined
and tested for attained component properties and their performance under stress on the
pipe-liner-compound.
Here the following separate tests were executed:
3.1.Characteristic component values of the GFRP short liner
The examination of the material properties of short liners in hardened state took place
during the vertical crushing test (DIN EN 1228 -short term test)on liners DN 250 with a
test length of L =300mm.
In order to determine a possible influence by laminate overlapping the liner sections were
turned by 90°after each one load and loaded until a vertical deformation of 3,5%took
place.
Elntellunq der MaBpunkta:
\
'2.Krafteinteitung
urn 90'versetzt bis 3.5%
Belastung derAbschnitte bis
zum Bruch (Maximalkraft)
Result
load on pipe sections until a vertical deformation of 3,5%took place
test
ring stiffness at 3%
deformation Sr
ring stiffness at 3%
deformation Sr
circumferential Young's
modulus Eo
circumferential Young's
modulus Eo
wall thickness s
1.load appl.
2.load appl.
1.load appl.
2.load appl.
standard
DIN EN 1228
unit
N/mm2
N/mm2
N/mm2
N/mm2
mm
value
0.025
0.023
9,770
9,137
3.62
ING.-B0RO
ROLFSIEBERT
CS3 040/739141
EH 040/7394277
GFRP shortliners and hoods
materials and component testing
page 4
report no.:
SVB 97.20471 S
load on pipe sections at breaking point
test
vertical crushing strength
Fmax
line break load
ring bending tensile strength aRR7
ring stiffness at 3%deformation Sr
circumferential young's module
En
wall thickness s
standard
DIN EN 1228
unit
N
kN/m
N/mm*
N/mm*
N/mm2
mm
value
2581
8.6
159
0.024
9.640
3.62
In the further course of the test the pipe liners,after exceeding the max.vertical load,
were deformed even more until 40%vertical deformation without any visible delaminationorbreakingsoccurring.
3.2.Performance of GFRP short liners when installed
For the conduction of the test the interior wall of a vitrified clay pipe DN 250 was cleaned
and mechanically roughened with a grinding brush so that sufficient adhesion to the shortlinercouldbeprovided.
As a bond between the GFRP short liner and the interior wall of the old pipe,and foroptimisingtheadhesionforce,a 2-component epoxy mortar (cold curing)is spread on theGFRPlaminatecutthatwasplacedontheapplicationunit.
The hardening of the liner and the epoxy mortar takes place simultaneously,supported by
the reaction temperature of the liner matrix.
The examination of the mechanical properties of the installed short liner took place in theverticalcrushingtest(DIN EN 1228 -short time test)on pipe sections with a test length of
L =300mm (picture 1).•=■
,5.8 -6.5 mm
28.67 mm
verklebta BrOche
STZ-Rohr DN 300 Klassa 200
Kurztiner
ing.-bOro
rolf siebert
CS3 040/739141
IBS 040/7394277
GFRP shortliners and hoods
materials and component testing
page 5
report no.:
SVB 97.20471 S
*Forthe test vitrified clay pipes DN 250 (DIN EN 295-1)ofstrength class 160 =40 KN/m were used.
Result
pipe
testing state
basic data
GFRP short liner
vitrified clay pipe
DN250
system
short liner/vitrified
clay pipe (Fig.1)
system
short liner/vitrified
clay pipe after
breaking of vitrified
clay pipe (Fig.2)
vertical crushing
load
Fmax (kN/m)
8.6
48.4
51.5
8.5
ring stiffness
SR (N/mm1)
0.024
0.677
0.06 liner
0.6 vit.clay
0.060
ring bending tensile
strength
orbz (N/mm2)
159
23
26.2
194.7
circumferential
Young's modulus
Eo(N/mm2)
9,640
-35,000
~35,000
14.500
During the tests good adhesion of the pieces of vitrified clay to the GFRP laminate was
observed.
The pieces (after rupture of the vitrified clay pipe)sticking to the liner had a supporting
effect so that the ring stiffness of the GFRP liner and the ring bending tensile strength
were higher than the initial value (Fig.3).
With all test specimens the vertical crushing tests were continued until the laminate failure
of the short liner.
By means of load introduction first only the stiff pipe was stressed until breaking
deformation,and afterwards the system pipe /GFRP short liner was stressed up to
rupture.
Only when the support provided by the vitrified clay pieces was"not given any more,
further load on the GFPR short liner was applied up to failure.(Fig.4).
3.3.Bond shear strength of the short liner in the pipeline
In order to determine the attainable adhesion of the pipeline wall to the GFRP short liner
using also epoxy mortar compound adequate bonds were made with sections of pipe
walls under construction site conditions.Furthermore tear-off tests as shear tension tests(DIN 53 455)were carried out.
In these tests the roughened pipe wall was bonded with the short liner laminate in dry
state,in wet state and under the influence of a water-oil emulsion.
ING.-BUHO
ROLFSIEBERT
C2D 040/739141
040/7394277
GFRP shortliners and hoods
materials and component testing
page 6
report no.:
SVB 97.20471 S
Result
test arrangement
epoxy compound in vitrified
clay pipe
roughened surface
dry surface
epoxy compound in vitrified
clay pipe
roughened surface
wet surface
epoxy compound in vitrified
clay pipe
roughened surface
wet /oily surface
remark
only vitrified clay pipe
broken,
no separation from
vitrified clay pipe
only vitrified clay pipe
broken,
separation from the
vitrified clay pipe
all bonds came loose
on the vitrified clay
pipe
cj-Max (N/mm1)
6.8
6.0
2.3
The results of the shear tension test showed that the surface of the pipe to be lined needs
to be cleaned carefully (oil-free)and roughened if necessary.The presence of humidity
had only little influence on the adhesion of the liner matrix to the old pipe.
4.Conclusion
The short liner method developed for partial repair of sewers and sewage pipelines on the
basis of previously impregnated and physically thickened GF-UP resin mats can be used
without any problems under construction site conditions.
When installed the liner sections and liners produced during field tests and examined in
the test laboratory of the expert showed a performance typical for GF-UP normal
laminates with sufficient adhesion to the interior pipe wall areas of the old sewer.
The ring stiffness attained even with low wall thickness (s a 3 mm)allows you to fix even
structural damage on the pipeline while guaranteeing the operating safety of the sewer.
Oststeinbek,26th September,1997revisedon12thApril,2001
enclosures:
Fig.1-4
test records
''■":■"''.DO"'
CONSULTING ENGINEERS FOR PLASTICS ENGINEERING
ROLF SiEBERT
APPLICATION ENGINEERING
QUALITY ASSURANCE
MATERIAL INSPECTION
Expert publicly commissioned and assigned
by the Chamber of Commerce and Industry
for LQbeck for application and inspection of
reinforced plastics and thermoplastics for
disposal plants for waste water and waste
material
Schulstrasse 22
22113 Oststeinbek /Hamburg
Tel 040/739141
FAX 040/7394277
Report of the authorized inspector
SVB-No.:96.00457 S
UP-prepregs for manufacturing GFK-short liners and scoops
Instructions for transportation,storage and handling at worksite
Certificate of eco-compatibility
Client:
Cosmic
Johann KQbel,Engineer
Steinabruck 35
A-3072 Kasten
Contents:
1.Supply state of UP resin
2.Manufacturing and advanced processing of the UP prepregs (SMC)
This report contains 3 pages (incl.covering letter)andmaybeduplicatedonlywithawrittenconsentfromtheexpert.
SMC Short Liners and Scoops
Certificate of Eco-compatibility
PageiENGG.OFFICE
ROLFSIEBERT
Tel:040/739141
Fax:040/7394277 -SVB No.96.00457 S
1.Supply state of the UP resin
Polyester resin material,which is used for manufacturing hose liners,should have a monomerStyrenecontentof40%to max.49%in their supply state.
The viscosity ofthis resin without any extra additives is approximately 90 seconds /> 300 m Das(DIN 53 221).The flashpoint is 34°C (DIN 53 213).
The Styrene contained in the polyester resin has been classified under water endangerment classWGKIIasperthehouseholdwatersupplyact(WHG).Any classification ofthe fully processed UPresinisnotavailableinastandardizedform,however the same is primarily achieved likewise as perWGKII.
A specification catalog and a safety information sheet for the resin used are available forviewingattheprocessingplant.
According to the ocean freight regulation (SFO)and the railway transport regulation
(EVO),such preparations of UP resins are assigned the marginal code 1350 and areclassifiedunderpoint3oftheclassIIIa.
The UP resin in this supply state is transported from the manufacturer's site to the
production plant for hose liners but is not transported again on road with the same
composition.
2-Manufacture and advanced processing of the UP resin oreprens fSMCl
Manufacture ofthe UP resin prepregs then takes place in the fabrication department bywayofimpregnatingtextileglassmatswithaspeciallypreparedpolyesterresin.
The composition of the UP resin is then altered by way of addition of inorganic fillingmaterialsandthroughdistributionofmassinthetextileglassmeshesorglassfiber
complexes.
The SMC laminate used in the tunnel redevelopment work is composed of:
Resin matrix
Thixotropic and thickening agents
Additives
Glass fiber reinforcinQ material
Styrene content of about 25%(max.)of the total mass
Specific weight of the total mass 1.55
The curing system of the linear laminate is designed with UV light in a definite nanometerrange,owing to which any uncontrollable reaction during transportation can take its effectonlyafterarelativelylongertimeandsignificantexternalheatingeffectandthattooinaveryhaltingmanner.
ENGG.OFFICE
ROLFSIEBERT
Tel:040/739141
Fax:040/7394277
SMC Short Liners and Scoops
Certificate of Eco-compatibility
Page 2
SVB No.96.00457 S
Since the material configuration and the properties ofthe relining hose molding compound match or
are very similar to those of a fiber molding material,the classification for this product is to be done
as per the DIN safety sheet for fiber molding materials.Following this,the UP prepreg semi-finished
product need not be treated as a hazardous transportation material anymore.
The physicallythickened UP prepreg is then fastened in a lightproof blister pack and additionally in a
wear-resistant packaging foil for its transportation and storage at the production site.
With this,the possibility of any endangerment of underground water through handling and storage of
the not-yet-cured linear laminate at the production site can be ruled out
While mounting the respective short liners custom-made forthe particular areas of application,the
non-cured laminate is compression-molded by the packer against the wall of the tunnel during the
compression process.
The highly viscous and almost dry state of the matrix makes it impossible forthe non-cured portionoftheresintooozeoutthroughthecracks,which probably exist
Subjecting to irradiation by UV-beam results in a spontaneous curing of the resin matrix.
Once the curing of the liner or the scoop is complete,the molded material is then considered water-insoluble and reacts neutrally to its surroundings.
Hardened residue materials are considered as industrial waste similarto household waste and canbedisposedofjustlikehouseholdwaste.
Oststeinbek,28*November 1996
Cosmic-Sondentiaschinenbaa Gmbll/A-3072 Kasten
Tel:+43 2744 7004/www.cosmic.al
Dieses Dokument is!urlieberreclillich gescliiitzt.smic:-.:■;-
Testing:
The two attachments are tests performed by:
Ingenieurbttro Fttr Kunststofftechnik
Schulstrassc 22
22113 Oststeinbek/Hamburg
Germany
The tests document the Cosmic fiberglass laminate has:
Short Term Modulus of Elasticity =Es=9,640 N/mm2 -
1.4xlO6Psi
Bonding to dry VCP clay pipe =6.8 N/mm2 «986 Psi
Bonding to moist VCR clay pipe -6.0 N/mm2 =870 Psi
Bonding to clay pipe wetted by oil emulsion =23 N/mm2 «333 Psi